Arsenic
Removal Technology Installed Despite Limited Time and Space
By Joseph Ritter and Robert Germon, Aqua Pennsylvania,
Inc., and Rich Dennis, Severn Trent Services
In
2001 Aqua Pennsylvania, Inc., one of the country’s largest
investor-owned water utilities, began development on the Meyers Tract
well system, a new water treatment facility in Collegeville, Pa. Testing
on the source wells revealed elevated arsenic (As) levels, measuring
approximately 12 µg/L in one well, and about 15 µg in the
second well. Although these levels did not exceed the 2001 arsenic maximum
contaminant
level (MCL) of 50 µg/L, Aqua Pennsylvania knew the U.S. Environmental
Protection Agency (EPA) would be lowering the MCL for arsenic
in drinking water to 10 µg/L in January 2006 and that some type
of treatment would be needed if this supply was to remain available to
the public.
Finding the best treatment technology to address the problem was just
one of the challenges facing the company. Aqua Pennsylvania also needed
to find equipment that would fit into its existing facility and that
could be manufactured, delivered and installed in time for the heavy
demand of the summer months.
Zoning restrictions did not allow for expansion of the footprint of the
well water treatment facility, so a system had to be found that would
operate within the existing building. The available space in the building
was about 20 feet long by 12 feet wide by nine-and-a-half feet high,
and access to the equipment had to be available within this footprint.
Since Aqua Pennsylvania did not have a discharge permit for the suburban
Philadelphia site or access to sewers for any innocuous water, the As
removal process could not generate a significant amount of wastewater.
The company initiated a program piloting different types of As removal
processes. Most of the arsenic removal systems being considered would
have required up to double the available space for chemical feed storage
and wastewater tanks. The system chosen was Severn Trent Services’ SORB
33™ As Removal System, which fit neatly into the existing space.
At the heart of the SORB 33 system design is the Bayoxide® E33 iron-based
adsorption media developed by LANXESS (formerly Bayer AG) in cooperation
with Severn Trent. The media has a high capacity for arsenic and, unlike
other iron-based adsorptive media, is delivered in a dry crystalline
form. The granular ferric oxide Bayoxide E33 product is robust, easy-to-handle
and has NSF Standard 61 approval.
During system operation, water from the source well is pumped through
a fixed bed pressure vessel, or series of vessels, containing the Bayoxide
E33 media. As the water passes through the fixed bed of media, the arsenic
is removed to less than 10 µg until the media reaches its capacity.
The spent media – which passes the Toxicity Characteristic Leachate
Procedure (TCLP) test categorizing it as non-hazardous – is then
removed and disposed of as non-hazardous waste. Unlike several other
As removal technologies, there is no complex on-site regeneration or
flocculation, making the SORB 33 process simple and reliable while minimizing
labor and operator skill requirements. The media’s high capacity
for arsenic enables long operating cycles of six to 24 months between
media change-out, thus minimizing operational and maintenance requirements.
The skid-mounted SORB 33 system is 164 inches long by about 77 inches
wide and 114 inches high. Because of its standard packaged design, the
system was fabricated and shipped to the Meyers Tract site less than
two months after the order was placed. The system was shipped as a unit,
partially disassembled, brought in through a six-feet-wide by seven-feet-high
double door, and reassembled inside the building. Other work included
partial interior modifications of the building and relocating chemical
feed and other equipment while keeping the station in service, with only
minor shut downs for tie-in to the new equipment. A hatchway also was
installed in the building roof to facilitate gravity media fill into
the adsorber vessels directly from large sacks.
The construction, delivery and installation took three months – approximately
one to two months less than would typically be expected for such a project.
The station was placed into service in July 2004. Since the beginning
of its operation, the system has produced water with an arsenic level
of less than 2.0 µg, which is the laboratory detection limit for As.
The only maintenance required, as expected, has been the occasional “backwash” or “fluffing” of
the beds every few months. It’s anticipated that the media will
require replacement in approximately two years.
The SORB 33 system allowed Aqua Pennsylvania to rapidly install a system
to meet the summer loading needs of the area while meeting municipal
zoning restrictions. And while reducing As levels to below the new MCL
of 10 µg was the primary goal of installing the system, SORB 33
has far exceeded expectations by helping reduce As levels to below the
level of laboratory detection.
For more information, contact Severn
Trent Services at info@severntrentservices.com.